
A brand new expertise has been developed that allows the manufacturing of skinny movies, which usually require advanced processes, utilizing solely water and oil in only one minute. Professor Kang Hee Ku and her analysis workforce from the Faculty of Power and Chemical Engineering at UNIST introduced their novel course of for creating catalytic skinny movies utilizing oil droplets dispersed in water.
The developed expertise includes a course of wherein nanomaterial precursors hooked up to the floor of oil droplets float to the floor of the water, the place they assemble into a skinny movie. When hydrogen peroxide is added, it decomposes as a result of skinny movie precursors, producing fuel bubbles that trigger the precursors to be lifted and assembled on the water floor inside one minute.
This course of permits for exact management of the skinny movie thickness, adjustable from 350 μm, and permits the synthesis of skinny movies protecting an space of as much as 100 cm² utilizing varied uncooked supplies. The ensuing skinny movies exhibit a porous construction with a excessive floor space, that includes distinctive mechanical power and suppleness.
Moreover, these skinny movies have a dense binding construction that enables for straightforward switch from the water floor to substrates utilizing a lift-on technique, with out harm. Sometimes, the switch course of can result in harm even when manufacturing high-quality skinny movies. This has been demonstrated via experiments involving the switch of skinny movies onto substrates of assorted kinds and supplies, together with these with intricate patterns on the micrometer scale, permitting for exact coating.
The analysis workforce utilized carbon nanomaterials coated with platinum (Pt/C) as uncooked supplies to supply catalytic skinny movies, which have been then transferred onto a leaf for gold plating to create versatile electrodes. These electrodes demonstrated constant conductivity adequate to energy a miniature gentle bulb even below repeated bending. The analysis is revealed in ACS Nano.
Professor Ku defined, “This expertise represents a paradigm shift using Pickering emulsions, that are utilized in cosmetics manufacturing.” Pickering emulsions decrease interfacial power by protecting the interface of water and oil with strong nanoparticles (NPs) as a substitute of utilizing molecular surfactants.
The workforce developed a brand new platform by leveraging the idea that it’s energetically favorable for these NPs to spontaneously transfer from the oil-water interface to the air-water interface for meeting.
She additional added, “The method just isn’t solely cost-effective but additionally permits for a spread of NP combos and is substrate-agnostic, making it relevant within the growth of versatile electrodes, catalysts, and power storage units.”
Extra info:
Jieun Heo et al, Scalable Fabrication of Freestanding Jammed Nanoparticle Movies through Pickering Emulsion-Mediated Interfacial Meeting, ACS Nano (2025). DOI: 10.1021/acsnano.4c13566
Quotation:
Revolutionary expertise permits fast skinny movie manufacturing in a single minute utilizing solely water and oil (2025, March 21)
retrieved 22 March 2025
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