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Revolutionary doping approach boosts semiconductor nanocrystal efficiency


Successfully developed a method for doping semiconductor nanocrystals, synthesizing next-generation semiconductor nanomaterials from the seed phase to the future!
Synthesis and characterization of 2D Mn-doped ZnSe quantum nanoribbons. a) Schematic displaying the synthesis of Mn-doped ZnSe quantum nanoribbons. b) Low-resolution, c,d) side-view, and e) high-resolution TEM photographs of Mn-doped ZnSe quantum nanoribbons (xMn = 12%). f) Absorption, PL, and PLE spectra of Mn-doped ZnSe quantum nanoribbons (xMn = 7%). g) Experimental okay2-weighted Zn and Mn Ok-edge EXAFS oscillations, h) Fourier-transformed EXAFS spectra with their fittings based mostly on tetrahedral symmetry, and that i) Fourier-filtered EXAFS spectra (xMn = 12%). Credit score: Small Science (2024). DOI: 10.1002/smsc.202400300

A analysis workforce has efficiently developed a brand new know-how to regulate doping on the nucleus (seed) section to extend the efficiency of semiconductor nanocrystals. The examine uncovered how the doping course of and site differ relying on the kind of doping component (dopant). The developed know-how is predicted to be extensively utilized in superior digital units, equivalent to shows and transistors.

With the fast improvement of superior applied sciences in recent times, equivalent to shows and transistors, curiosity in applied sciences that may exactly management doping in nanoscale semiconductors is rising. Particularly, II-VI semiconductor-based nanocrystals have been extensively studied owing to their excellent optical and .

Whereas doping performs a important position in semiconductor know-how, the issue of low doping effectivity in small semiconductors, equivalent to nanocrystals, stays. This drawback arises as a result of dopants are typically absorbed onto the floor of a semiconductor throughout its development and don’t penetrate its inside successfully.

On this context, DGIST Professor Jiwoong Yang’s analysis workforce developed a managed nucleation doping methodology, which induces doping on the “nanocluster” section, a stage previous nanocrystal development. Utilizing this system, the workforce efficiently applied secure and exact doping in ZnSe semiconductor nanocrystals and recognized the explanations behind the variations in doping processes and places relying on the dopant sort.

The work is revealed within the journal Small Science.

Though earlier research on doping II-VI nanocrystals have primarily used CdSe, a , Cd is dangerous to the surroundings and has poor stability. This examine developed a know-how relevant to nanocrystals that eliminates the usage of heavy metals, demonstrating its potential for sensible functions whereas additionally addressing environmental considerations. As well as, the examine demonstrated the know-how’s applicability throughout numerous digital units, equivalent to shows and transistors.

Professor Yang mentioned, “This analysis has enabled us to systematically set up doping management know-how in nanocrystals. The findings is not going to solely function essential foundational knowledge for designing and fabricating optoelectronic units, equivalent to next-generation shows and transistors, but additionally open up new prospects for designing progressive units via exact management know-how.”

This examine was performed in collaboration with a analysis workforce led by Stefan Ringe on the Division of Chemistry, Korea College (Dongwon Kim).

Extra data:
Seunghyun Ji et al, Nucleation‐Managed Doping of II–VI Semiconductor Nanocrystals Mediated by Magic‐Sized Clusters, Small Science (2024). DOI: 10.1002/smsc.202400300

Quotation:
Revolutionary doping approach boosts semiconductor nanocrystal efficiency (2025, January 6)
retrieved 6 January 2025
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