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Monday, February 24, 2025

Nanoscopic cross-grain cation homogenization in perovskite photo voltaic cells


  • Kojima, A., Teshima, Ok., Shirai, Y. & Miyasaka, T. Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. J. Am. Chem. Soc. 131, 6050–6051 (2009).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Jiang, Q. et al. Floor response for environment friendly and secure inverted perovskite photo voltaic cells. Nature 611, 278–283 (2022).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Zhao, Y. et al. Inactive (PbI2)2RbCl stabilizes perovskite movies for environment friendly photo voltaic cells. Science 377, 531–534 (2022).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Zhou, Y. et al. Advances and challenges in understanding the microscopic construction–property–efficiency relationship in perovskite photo voltaic cells. Nat. Vitality 7, 794–807 (2022).

    Article 
    CAS 

    Google Scholar
     

  • Min, H. et al. Environment friendly, secure photo voltaic cells through the use of inherent bandgap of α-phase formamidinium lead iodide. Science 366, 749–753 (2019).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Koh, T. M. et al. Formamidinium-containing metal-halide: an alternate materials for near-IR absorption perovskite photo voltaic cells. J. Phys. Chem. C 118, 16458–16462 (2014).

    Article 
    CAS 

    Google Scholar
     

  • Pellet, N. et al. Blended-organic-cation perovskite photovoltaics for enhanced solar-light harvesting. Angew. Chem. Int. Ed. 53, 3151–3157 (2014).

    Article 
    CAS 

    Google Scholar
     

  • Zheng, X. et al. Improved section stability of formamidinium lead triiodide perovskite by pressure leisure. ACS Vitality Lett. 1, 1014–1020 (2016).

    Article 
    CAS 

    Google Scholar
     

  • Wang, Y. et al. Unlocking the ambient temperature impact on FA-based perovskites crystallization by in situ optical methodology. Adv. Mater. 36, 2307635 (2023).

    Article 

    Google Scholar
     

  • Li, Z. et al. Stabilizing perovskite constructions by tuning tolerance issue: formation of formamidinium and cesium lead iodide solid-state alloys. Chem. Mater. 28, 284–292 (2016).

    Article 

    Google Scholar
     

  • Yi, C. et al. Entropic stabilization of combined A-cation ABX3 metallic halide perovskites for prime efficiency perovskite photo voltaic cells. Vitality Environ. Sci. 9, 656–662 (2016).

    Article 
    CAS 

    Google Scholar
     

  • Jacobsson, T. J. et al. Unreacted PbI2 as a double-edged sword for enhancing the efficiency of perovskite photo voltaic cells. J. Am. Chem. Soc. 138, 10331–10343 (2016).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Hao, M. et al. Ligand-assisted cation-exchange engineering for high-efficiency colloidal Cs1−xFAxPbI3 quantum dot photo voltaic cells with decreased section segregation. Nat. Vitality 5, 79–88 (2020).

    Article 
    CAS 

    Google Scholar
     

  • Liang, Z. et al. Homogenizing out-of-plane cation composition in perovskite photo voltaic cells. Nature 624, 557–563 (2023).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Bai, Y. et al. Initializing movie homogeneity to retard section segregation for secure perovskite photo voltaic cells. Science 378, 747–754 (2022).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Huang, J., Xu, P., Liu, J. & You, X.-Z. Sequential introduction of cations deriving large-grain CsxFA1xPbI3 skinny movie for planar hybrid photo voltaic cells: perception into phase-segregation and thermal-healing habits. Small 13, 1603225 (2017).

    Article 

    Google Scholar
     

  • Li, N. et al. Microscopic degradation in formamidinium-cesium lead iodide perovskite photo voltaic cells below operational stressors. Joule 4, 1743–1758 (2020).

    Article 
    CAS 

    Google Scholar
     

  • Liu, L. et al. A-site section segregation in combined cation perovskite. Mater. Rep. Vitality 1, 100064 (2021).

    CAS 

    Google Scholar
     

  • Mullins, W. W. Idea of thermal grooving. J. Appl. Phys. 28, 333–339 (2004).

    Article 

    Google Scholar
     

  • Zhao, B., Shvindlerman, L. & Gottstein, G. Line pressure of grain boundary triple junctions within the copper tricrystals. In TMS 2014: 143rd Annual Assembly & Exhibition 1063–1068 (Springer, 2016).

  • Hao, M. et al. Flattening grain-boundary grooves for perovskite photo voltaic cells with excessive optomechanical reliability. Adv. Mater. 35, 2211155 (2023).

    Article 
    CAS 

    Google Scholar
     

  • Yan, N., Fang, Z., Dai, Z., Feng, J. & Liu, S. Buried interface—the important thing points for prime efficiency inverted perovskite photo voltaic cells. Adv. Funct. Mater. 34, 2314039 (2024).

    Article 
    CAS 

    Google Scholar
     

  • Dong, Q. et al. Interpenetrating interfaces for environment friendly perovskite photo voltaic cells with excessive operational stability and mechanical robustness. Nat. Commun. 12, 973 (2021).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Zhao, L. et al. Enabling full-scale grain boundary mitigation in polycrystalline perovskite solids. Sci. Adv. 8, eabo3733 (2022).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Hackl, Ok., Fischer, F. D. & Svoboda, J. A variational strategy to the modelling of grooving in a three-dimensional setting. Acta Mater. 129, 331–342 (2017).

    Article 
    CAS 

    Google Scholar
     

  • Mullins, W. W. The impact of thermal grooving on grain boundary movement. Acta Metall. 6, 414–427 (1958).

    Article 

    Google Scholar
     

  • Saylor, D. M. & Rohrer, G. S. Measuring the affect of grain‐boundary misorientation on thermal groove geometry in ceramic polycrystals. J. Am. Ceram. Soc. 82, 1529–1536 (1999).

    Article 
    CAS 

    Google Scholar
     

  • Correa-Baena, J.-P. et al. Homogenized halides and alkali cation segregation in alloyed organic-inorganic perovskites. Science 363, 627–631 (2019).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Macpherson, S. et al. Native nanoscale section impurities are degradation websites in halide perovskites. Nature 607, 294–300 (2022).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Guthrey, H. & Moseley, J. A overview and perspective on cathodoluminescence evaluation of halide perovskites. Adv. Vitality Mater. 10, 1903840 (2020).

    Article 
    CAS 

    Google Scholar
     

  • Taylor, E. J. et al. Hyperspectral mapping of nanoscale photophysics and degradation processes in hybrid perovskite on the single grain stage. Nanoscale Adv. 5, 4687–4695 (2023).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Yang, J. et al. Understanding the position of cesium on chemical complexity in methylammonium-free metallic halide perovskites. Adv. Vitality Mater. 13, 2202880 (2023).

    Article 
    CAS 

    Google Scholar
     

  • Chen, J. et al. Environment friendly and vivid white light-emitting diodes based mostly on single-layer heterophase halide perovskites. Nat. Photon. 15, 238–244 (2021).

    Article 
    CAS 

    Google Scholar
     

  • Ma, F. et al. Steady α/δ section junction of formamidinium lead iodide perovskites for enhanced near-infrared emission. Chem. Sci. 8, 800–805 (2017).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Lai, M. et al. Structural, optical, and electrical properties of phase-controlled cesium lead iodide nanowires. Nano Res. 10, 1107–1114 (2017).

    Article 
    CAS 

    Google Scholar
     

  • Wang, P. et al. Seed-assisted development of methylammonium-free perovskite for environment friendly inverted perovskite photo voltaic cells. Small Strategies 6, 2200048 (2022).

    Article 
    CAS 

    Google Scholar
     

  • Chen, Y. et al. Pressure engineering and epitaxial stabilization of halide perovskites. Nature 577, 209–215 (2020).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Saidaminov, M. I. et al. Multi-cation perovskites stop service reflection from grain surfaces. Nat. Mater. 19, 412–418 (2020).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Tao, S. et al. Absolute vitality stage positions in tin- and lead-based halide perovskites. Nat. Commun. 10, 2560 (2019).

    Article 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Narra, S. et al. Femtosecond transient absorption spectra and dynamics of service leisure of tin perovskites within the absence and presence of components. J. Phys. Chem. Lett. 11, 5699–5704 (2020).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Yang, L. et al. Document-efficiency versatile perovskite photo voltaic cells enabled by multifunctional natural ions interface passivation. Adv. Mater. 34, 2201681 (2022).

    Article 
    CAS 

    Google Scholar
     

  • Duan, T. et al. Chiral-structured heterointerfaces allow sturdy perovskite photo voltaic cells. Science 384, 878–884 (2024).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Ren, Y. et al. A spiro-OMeTAD based mostly semiconductor composite with over 100 °C glass transition temperature for sturdy perovskite photo voltaic cells. Nano Vitality 81, 105655 (2021).

    Article 
    CAS 

    Google Scholar
     

  • Xiao, T. et al. Elimination of grain floor concavities for improved perovskite thin-film interfaces. Nat. Vitality 9, 999–1010 (2024).

    Article 
    CAS 

    Google Scholar
     

  • Jiang, Q. et al. In direction of linking lab and area lifetimes of perovskite photo voltaic cells. Nature 623, 313–318 (2023).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Chen, Y. et al. Nuclei engineering for even halide distribution in secure perovskite/silicon tandem photo voltaic cells. Science 385, 554–560 (2024).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Zhao, B., Ziemons, A., Shvindlerman, L. S. & Gottstein, G. Floor topography and vitality of grain boundary triple junctions in copper tricrystals. Acta Mater. 60, 811–818 (2012).

    Article 
    CAS 

    Google Scholar
     

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